导 师 简 介
李湘广,男,昆明学院副教授/硕士生导师,云南省高校有机光电子材料与器件重点实验室副主任,云南省中青年学术和技术带头人后备人选、昆明市“春城计划”春城青年拔尖人才、昆明市中青年学术和技术带头人后备人选等。云南省科技专家。
近年来,主持国家自然科学基金项目2项,省部级项目4项。在Chem. Commun., J. Mater. Chem. C, J. Org. Chem.等期刊发表SCI论文30余篇,授权国家发明专利1件。获云南省自然科学三等奖1项。
李湘广导师详细介绍
一、个人基本情况
李湘广,男,出生于1985年12月,籍贯:湖南永州,中共党员。
二、主要学习经历
2004.09-2008.07 中国 西北大学 化学 学士
2008.09-2011.07 中国 西北大学 有机化学 硕士
2011.09-2014.07 中国 中国科学院大学 有机化学 博士
三、主要工作经历
2014.09-至今 中国 昆明学院 教师
四、主要研究方向
1. 含氟硼类近红外荧光染料的设计合成
2. 分子器件(有机场效应晶体管、有机太阳能电池)
五、主持科研项目
1. 基于BODIPY的高性能有机染料敏化剂的合成策略及光伏性能研究,22065019,国家自然科学基金项目,2021/01-2024/12,40万元
2. 新型近红外非金属染料敏化剂的合成及性能研究,21502077,国家自然科学基金,2016/01-2018/12,21万元
3. 云南省中青年学术和技术带头人项目,202105AC160043, 2021/01-2025/12,6.00万元
4. 高性能染料敏化剂的合成策略及光伏性能研究,202001BA070001-010,云南省地方高校基础研究联合专项重点项目, 2020/01-2022/12,40万元
5. 基于D-A-π-A染料结构的高性能染料敏化太阳能电池,2018FB020,云南省科技厅面上项目,2018/06-2021/05,10万元
6. 昆明市“春城计划”春城青年拔尖人才专项,C202014001,2021/01-2025/12,50万元
六、荣誉/获奖
1. 昆明学院校级优秀教师(2023.9.7)
2. 昆明学院二层次人才激励计划(2023.4.6)
3. 云南省自然科学三等奖(2022.5.17)
4. 清华大学国内访问学者(2021.9-2022.7)
5. 昆明市“春城计划”春城青年拔尖人才(2021.5.17)
6. 云南省省中青年学术和技术带头人后备人才(2020-2025)
7. 云南省第十六届职工职业技能大赛——“高教社杯”高等师范院校化学教师教学技能大赛三等奖(2019.11.15)
8. 昆明市中青年学术和技术带头人后备人选(2018.12.29)
9. 昆明学院青年骨干教师(2017.9-2020.8)
七、主讲课程
《有机化学》、《高分子化学》、《有机化学实验》
八、发表学术论文/专著
2024年发表文章:
1、Jie Li, Ning Xue, Shulin Gao, Yanhua Yang, Zhehui Weng, Haidong Ju, Zhaohui Wang, Xiangguang Li*, and Wei Jiang*. Dithio-fused boron dipyrromethenes: synthesis and impact of S‑heteroaromatic annulation mode. Org. Lett. 2024, 26, 26, 5472-5477.
2、Limin He, Lu Li, Muyao Zhao, Yunxia Zhao, Yanqing Li, Xiangguang Li,* Yanhua Yang,* Shulin Gao, Ping Lei, Zhaohui Wang and Wei Jiang*. Dibenzothieno and dibenzothieno[2,3-d]thieno [a]-fused BODIPYs: synthesis, unique structure and photophysical properties. Mater. Chem. Front. 2024, DOI: 10.1039/d4qm00616j.
3. Rui Liang, Guanchen Dong, Jiazhuang Tian, Shulin Gao, Yanhua Yang*, Baoling Wang**, Xiangguang Li***. Study on mechanofluorochromism, ink-free writing, and latent fingerprint imaging of the functionalized difluoroboron compounds with methyl
and methoxy. Optical Materials 2024, 156, 115991
4、Sixiang Ding, Chi Zhang, Zhiheng Zhao, Limin He, Xiangguang Li*, Ganpeng Li*, Lijun Gu*. Electrochemical dehydrogenative phosphorothiolation of heteroarenes. Tetrahedron, 2024, 163, 134131.
5、Shuai Tan, Jiazhuang Tian, Shufan Yang, Bangcui Zhang, Yanhua Yang*, Xiangguang Li**, Shulin Gao***. Study on four pyridine-based difluoroboron compounds for mechanofluorochromic behaviors, the ink-free writing and detection of latent fingerprints. Journal of Luminescence, 2024, 275, 120730.
6、Jiazhuang Tian, Zhiyou Su, Xiaozhou Jiang, Bangcui Zhang, Yanhua Yang*, Xiangguang Li*, Gaozhang Gou*. Mechanofluorochromic behaviors and latent fingerprint detection of triphenylamine-based compounds with mono-/bis-BF2 fluorophores. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 2024, 319, 124568.
7、Shufang Yang, Jiazhuang Tian, Bangcui Zhang, Yanhua Yang*, Xiangguang Li*, Shulin Gao*, Lin Shao and Fumin Li. A difluoroboron compound with latent fingerprint detection and inkless writing based on aggregation-induced emission enhancement and mechanofluorochromic behavior. New J. Chem., 2024, 48, 1264-1271(IF=3.3)
8、胡仕婷,何丽敏,钱薏蓉,李湘广*,杨艳华*. C5-BODIPY的氧化及碘代反应研究. 云南化工, 2024, 51(7), 35-38.
9、何丽敏,周萧茂,刘黔希,曾静,李湘广*,杨艳华*,雷萍*. 1,5,9-三溴苯并菲的合成方法研究. 云南化工, 2024, 9, ASAP.
10、Wen Jiang, Wenming Hou, Caixian Yan, Zhifeng Nie, Qiaowen Chang*, Xiangguang Li* and Weiping Liu. Synthesis and performance of deep-red phosphorescent iridium complexes with pyrone as an auxiliary ligand. Molecules 2024, 29, 3183.
2023年发表文章:
1、Shufan Yang, Shuai Tan, Yanqin Chen, Jiazhuang Tian, Yanhua Yang*, Xiangguang Li*, Shulin Gao*. Effect of substituent position with different charge characteristics groups on mechanofluorochromic behaviors of the pridine-based difluoroboron compounds. Dyes and Pigments, 2023, 220: 111736.
2、Sihu Dou, Maocai Xu, Jiazhuang Tian, Bangcui Zhang, Shuling Gao, Yanhua Yang*, Baoling Wang, Xiangguang Li, Gaozhang Gou*, Mechanofluorochromic behaviours of functionalized carbazole-based difluoroboron compounds with different aryl substituents moieties, Luminescence, 2023, 38(8):1501-1510.(
3、张帮翠,何秀娟,徐茂财,李湘广,李艳妮,杨艳华*,高树林*,李福敏,邵林,一种含有吩噻嗪基团的二氟硼化合物荧光性能研究,云南民族大学学报(自然科学版),2023,https://kns.cnki.net/kcms/detail/53.1192.N.20220919.1934.004.html
2022年发表文章:
1、Ming Li, Chi Zhang, Ya-Qin Zhou, Yang Liu, Na Zhao, Xiangguang Li*, Li-Jun Gu*, Electrochemical intramolecular haloheterocyclization reactions using 1,2-dihaloethanes as halogenating reagents, Tetrahedron Letters, 2022, 89, 153602
2、赵娜, 李杰, 杨艳华, 戴恩睿, 李湘广*. BODIPY二聚体及三聚体的一锅合成法及其性质研究, 昆明理工大学学报(自然科学版), 2022, 47(04), 110-117
3、Chenghan Li, Tingting Guo,* Mengke Guo, Yumin Song, Zhifeng Nie, Xiangguang Li, and Gang Yu*, Synthesis of Ultrathin AuPt Alloy Porous Nanowires with Abundant Electrocatalytic Active Sites for Excellent Electrocatalysts, J. Phys. Chem. C, 2022, 126, 30, 12472–12479.
2021年发表文章:
1、Zhiheng Zhao, Yonghui He, Ming Li, Jiazhe Xu, Xiangguang Li*, Lizhu Zhang,
Lijun Gu*, An electrochemical multicomponent [3 + 1 + 1] annulations to synthesize polysubstituted 1,2,4-triazoles, Tetrahedron, 2021, 87, 132111
2、Yuan Li, Xin Zhang, Deqiang Liang*, Yanni Li*, Shulin Gao, Xiangguang Li, Ying Dong, Baoling Wang, Yinhai Ma, Tunable Redox-Neutral Photocatalysis: Visible Light-Induced Arylperfluoroalkylation of Alkenes Regulated by Protons. Asian J. Org. Chem., 2021, 10(3): 642-648
2017年发表文章:
1、Xiangguang Li*, Deqiang Liang, Wenzhong Huang, Huanli Sun, Lvsu Wang, Mengran Ren, Baoling Wang, Yinhai Ma, Metal-free Photocatalyzed Cross Coupling of Aryl (Heteroaryl) Bromides with Isonitriles, Tetrahedron, 2017, 73(50): 7094-7099.
2、Deqiang Liang*, Yanni Li, Shulin Gao*, Renlun Li, Xiangguang Li, Baoling Wang and Hai Yang, Amide-Assisted Radical Strategy: Metal-Free Direct Fluorination of Arenes in Aqueous Media, Green Chem., 2017, 19(14): 3344-3349.
3、Yanni Li, Deqiang Liang*,Xiangguang Li, Wenzhong Huang, Lin Yuan, Baoling Wang, Ping Cheng, Br2- or HBr-catalyzed Synthesis of Asymmetric 3,3-di(indolyl)indolin-2-ones, Heterocyclic Communications, 2017, 23(1): 29-34.
4、Yanni Li, Deqiang Liang*, Yu Chang, Xiangguang Li, Shaoguang Fu, Yunli Yuan,
Baoling Wang. Metal-free and selective cleavage of unstrained carbon–carbon single bonds: Synthesis of β-ketosulfones from β-chlorohydrins and sodium sulfinates, Synth. Commun. 2017, 47(22): 2044–2052.
2016年发表文章:
1、Xiangguang Li*, Deqiang Liang*, Wenzhong Huang, Hongfu Zhou, Zhao Li, Baoling Wang,Yinhai Ma,Hai Wang, Visible Light-Induced Carbonylation of Indoles with Arylsulfonyl Chlorides and CO, Tetrahedron, 2016, 72(51): 8442-8448.
2、Deqiang Liang*, Xiangguang Li, Juan Yang, Yanni Li*, Baoling Wang, PingCheng, Experimental and Theoretical Study of I2-catalyzedDialkenylOxindolesSynthesis from Isatins and α-cyanoKetene Ethylene Dithioacetal, Synth. Commun., 2016, 46(23): 1924-1931.
3、Deqiang Liang*, Xiangguang Li*, Chaowu Wang, Qishan Dong, Baoling Wang, Hai Wang, Regioselective and Efficient Bromination of Anilides on Water Using HBr and Selectfluor, Tetrahedron Letters, 2016, 57(48): 5390–5394.
4、Zongrui Wang, Xiangguang Li(共同一作), Ye Zou, Jiahui Tan,Xiaolong Fu, Jie Liu, Chengyi Xiao,Huanli Dong*, Wei Jiang*, Feng Liu*, Yonggang Zhen, Zhaohui Wang*, Thomas P. Russell*,Wenping Hu*,Tuning Charge Transport from Unipolar (n-type) to Ambipolar in Bis(Naphthalene Diimide) Derivatives by Introducing π-conjugated Heterocyclic Bridging Moieties, J. Mater. Chem. C, 2016, 4(30): 7230-7240.
5、Deqiang Liang*, Xiangguang Li, Yanni Li,Yungang Yang,ShulinGao*,Ping Cheng, Br2-Catalyzed RegioselectiveDehydrativeCoupling of Indoles with Acyloins: Direct Synthesis of α-(3-Indolyl) Ketones, RSC Adv., 2016,6(35): 29020-29025.
6、Deqiang Liang*, Xiangguang Li, Wanshun Zhang, Yanni Li*, Mi Zhang,Ping Cheng, Br2 as a Novel Lewis Acid Catalyst for Friedel–Crafts Alkylation of Indoleswith α,β-unsaturated Ketones, Tetrahedron Letters, 2016, 57(9): 1027-1030.
7、Deqiang Liang*, Xiangguang Li, Qing Lan, Wenzhong Huang, Lin Yuan, Yinhai Ma, Tin Tetrachloride Pentahydrate-catalyzed RegioselectiveChlorohydroxylation of α,β-unsaturated Ketones in Water with Selectfluor as a Chlorine Source, Tetrahedron Letters, 2016, 57(20): 2207–2210.
8、Wenzhong Huang, Juan Yang, Xiangguang Li, Lin Yuan, Yinhai Ma, Qinglong Zhou, Deqiang Liang*, Catalyst-Free Synthesis of 3-(1-Arylsulfonylalkyl)indoles via Three-Component Reaction of Indoles, Carbonyls, and Arenesulfinic Acids. Phosphorus, Sulfur, and Silicon and the Related Elements, 2016, 191(5): 772-777 .
2015年发表文章:
1、Xiangguang Li, ZhiweiZheng, Wei Jiang*, Wenjun Wu*, Zhaohui Wang, He Tian, New D-A-π-A Organic Sensitizers for Efficient Dye-sensitized Solar Cells, Chem. Commun., 2015, 51(17): 3590-3592.
2、Xiangguang Li, Cheng Jin, LijunGu*, C-H Hydroxylation of Phosphonates with Oxygen in [bmIm]OH to Produce Quaternary α-Hydroxy Phosphonates, J. Org. Chem., 2015, 80(4): 2443-2447.
3、Xiangguang Li*, Wenzhong Huang, Deqiang Liang, Lin Yuan, Yinhai Ma, LijunGu*, Efficient Synthetic Route to Bisaryl Ketones via Copper-catalyzed C-C Triple Bonds Cleavage, Tetrahedron, 2015, 71(7): 1045-1049.
4、Wenzhong Huang, Lingli Nang, Xiangguang Li, Lin Yuan, Yinhai Ma, Deqiang Liang*, Bromine/para-Toluenesulfonic Acid-Catalyzed Synthesis of 3,3-Bis(indole-3-yl)indoline-2-(1H)-ones by Condensing Indoles with Isatins, Chin. J. Chem., 2015, 33(10): 1167-1172.
2014年发表文章:
1、Wei Jiang, Long Ye, Xiangguang Li, Chengyi Xiao, Fang Tan, Wenchao Zhao, JianhuiHou*, Zhaohui Wang*, Bay-linked PeryleneBisimides as Promising Non-fullerene Acceptors for Organic Solar Cells, Chem. Commun., 2014, 50(8): 1024-1026.
2、Chengyi Xiao, Wei Jiang*, Xiangguang Li, LinxiaoHao, Chunming Liu, Zhaohui Wang, Laterally Expanded RyleneDiimides with Uniform Branched Side Chains for Solution-Processed Air Stable n-Channel Thin Film Transistors,ACS Appl. Mater. Interfaces, 2014, 6(20): 18098-18103.
2013年发表文章:
1、Xiangguang Li, Chengyi Xiao, Wei Jiang*, Zhaohui Wang*, High-performance Electron-transporting Hybrid Rylenes with Low Threshold Voltage, J. Mater. Chem. C, 2013, 1(45): 7513-7518.
2、LijunGu*, Xiangguang Li, Microwave-Assisted Synthesis of Ethyl 1,3-Disubstituted-1,6-dihydropyrrolo[2,3-c]pyrazole-5-carboxylates,J. Heterocyclic Chem., 2013, 50(2): 408-412.
3、Xiangguang Li, Chengyi Xiao, Wei jiang, Zhaohui Wang, Synthesis and Properties of Hybrid RyleneDiimides, TRR61"Multilevel Molecular Assemblies: Structure, Dynamics and Function" international PhD-student-workshop, 53-54, Münster, Germany, 2013.6.7-2013.6.10. (国际会议)
2011年发表文章:
1、LijunGu*, Xiangguang Li, Microwave-Assisted Synthesis of Indole-2-Carboxylic Acid Esters in Ionic Liquid, J. Braz. Chem. Soc., 2011, 22(11): 2036-2039.
2010年发表文章:
1、LijunGu, Feilong Liu, Xiangguang Li, Bo Gao, Bingqin Yang*, Synthesis of Novel Bis-statine-based Peptide Containing Ferrocenyl Moiety, SyntheticCommun., 2010, 40(2): 242-246.
2、冷鑫; 李湘广; 李丽丽; 杨秉勤*,二茂铁环蕃的合成及其晶体结构,大环化学和超分子化学的新发展——当前学科交叉的一个重要桥梁——中国化学会全国第十五届大环化学暨第七届超分子化学学术讨论会论文摘要集,中国,重庆,2010-10-15(国内会议)
2009年发表文章:
1、李湘广,杨秉勤*,谷利军,宁伟. N-(酰基二茂铁)苯并咪唑类化合物的合成和表征. Chinese J ApplChem(应用化学), 2009, 26 (10): 1184-1188.
2、谷利军,杨秉勤*,刘飞龙,李湘广,刘小菊,高波. N-二茂铁乙酰基-Leu-Gly-OMe的合成. Chemical Reagents(化学试剂), 2009, 31(10): 773-774;777.
3、李湘广等. 2,7-二氨基-9,10-二氢-9,9-二甲基蒽的合成.中国化学会第六届有机化学学术会议论文集.西安:中国化学会第六届有机化学学术会议,2009:522
九、获得授权专利
2019年授权专利:
1、李湘广,张筱薇,谷利军,梁德强,黄文忠,马银海;吲哚-3-芳基酮衍生物的合成方法,2019-06-25, 中国, ZL201610764737.X.
十、联系方式
邮箱:lixiangguang@iccas.ac.cn
通讯地址:昆明市浦新路2号昆明学院北苑惟真楼3312
实验室:昆明学院北苑惟真楼3317
课题组网页:https://www.x-mol.com/groups/li_xiangguang
十一、其他内容
人生格言:只要路是对的,就不害怕遥远;只要认准是值得的,就不在乎沧桑变化。