导 师 简 介
梁德强,博士,教授,昆明市劳动模范,云南省有突出贡献优秀专业技术人才,云南省万人计划青年拔尖人才,云南省高校绿色有机资源化学科技创新团队带头人。研究方向是光电催化绿色有机合成。以第一作者或通讯作者发表SCI论文35篇,授权发明专利5项,主持国家自然科学基金2项、云南省科技厅项目3项。
梁德强导师详细介绍
一、个人基本情况
梁德强,男,博士,教授,1985年生,昆明市劳动模范,云南省有突出贡献优秀专业技术人才,云南省万人计划青年拔尖人才,云南省高校绿色有机资源化学科技创新团队带头人。研究方向是光电催化绿色有机合成。以第一作者或通讯作者发表SCI论文35篇,授权发明专利5项,主持国家自然科学基金2项、云南省科技厅项目3项。
2018年获得昆明学院第五届“挑战杯”大学生课外学术科技作品竞赛“先进个人”称号;2017年获得昆明学院第一届“突出贡献奖”科研贡献二等奖(一等奖空缺);2016年获得昆明学院“优秀班主任”称号、入选昆明学院青年骨干教师培养工程;2015年和2013年两次获得昆明学院青年教师课堂教学比赛理工科组一等奖;2013年获得云南省高等学校教师教育联盟首届青年教师课堂教学微课竞赛决赛一等奖、“红云园丁奖”优秀课堂教学奖。
二、主要学习经历
2007-9至2012-6,东北师范大学,有机化学,博士,导师:刘群、王芒教授
2003-9至2007-6,东北师范大学,化学教育,学士
三、主要工作经历
2019-7至现在,昆明学院,化学化工学院,教授
2018-9至2019-6,武汉大学,化学与分子科学学院,访问学者,合作导师:雷爱文教授
2012-7至2018-8,昆明学院,化学科学与技术系,讲师-教授
四、主要研究方向
光电催化有机合成、自由基化学、碳/杂环合成、烯烃双官能团化
五、主持科研项目
1. 国家自然科学基金委员会地区项目科学基金项目,光激发辅助的电化学碳/杂环合成,2021.01-2024.12
2. 国家自然科学基金委员会青年科学基金项目,酰胺氢协助策略:芳基自由基形成新方法及其应用,2018.01-2020.12
3. 云南省科学技术厅科技计划面上项目,基于烯胺双键捕获自由基的环合反应合成多取代1,3-二氢吡咯-2-酮,2019.08-2022.08
4. 云南省科学技术厅科技计划高校联合重点项目,新型自由基环化反应合成活性不饱和gamma-内酰胺,2019.01-2022.01
5. 云南省科学技术厅应用基础研究计划项目青年项目,非酸度依赖的新型催化sp2碳–碳偶联反应研究,2014.10-2017.09
6. 云南省教育厅一般项目,基于吲哚C3-烯基化/C2-偶联反应的吲哚增环反应研究,2013.07-2015.07
六、主讲课程
《有机化学》、《有机化学实验》、《论文写作与学术规范》等
七、发表学术论文/专著
1. Lichun Xu, Zhongxiao Ma, Xi Hu, Xin Zhang, Shulin Gao, Deqiang Liang,* Baoling Wang, Weili Li, Yanni Li,* Electroreductive synthesis of polyfunctionalized pyridin-2-ones from acetoacetanilides and carbon disulfide with oxygen evolution, Organic & Biomolecular Chemistry, 2022, 20, 1013–1018.
2. Rui Kong, Tingfeng Fu, Ruihan Yang, Danna Chen, Deqiang Liang,* Ying Dong, Weili Li, Baoling Wang, 4-Nitroanisole Facilitates Proton Reduction: Visible Light-Induced Oxidative Aryltrifluoromethylation of Alkenes with Hydrogen Evolution, ChemCatChem, 2021, 13, 2952–2958.
3. Zhongxiao Ma, Xiao Hu, Yanni Li, Deqiang Liang,* Ying Dong, Baoling Wang, Weili Li, Electrochemical oxidative synthesis of 1,3,4-thiadiazoles from isothiocyanates and hydrazones, Organic Chemistry Frontiers, 2021, 8, 2208–2214.
4. Yuan Li, Xin Zhang, Deqiang Liang,* Yanni Li,* Shulin Gao, Xiangguang Li, Ying Dong, Baoling Wang, Yinhai Ma, Tunable Redox-Neutral Photocatalysis: Visible Light-Induced Arylperfluoroalkylation of Alkenes Regulated by Protons, Asian Journal of Organic Chemistry, 2021, 10, 642–648
5. Yanni Li, Fengyuan Ying, Tingfeng Fu, Ruihan Yang, Ying Dong, Liqing Lin, Yinghui Han, Deqiang Liang,* Xianhao Long,* Heat- or light-induced acylarylation of unactivated alkenes towards 3-(α-acyl) indolines, Organic & Biomolecular Chemistry, 2020, 18, 5660–5665.
6. Enrui Dai, Yongrui Dong, Rui Kong, Guangzhang Liu, Ying Dong, Qiong Wu, Deqiang Liang,* Yinhai Ma, Transition-metal-free mono- or dinitration of protected anilines, Synthetic Communications, 2020, 50, 1687–1695.
7. Wenzhong Huang, Xiulan Li, Xuemei Song, Qing Luo, Yanping Li, Ying Dong, Deqiang Liang,* Baoling Wang, Benzylarylation of N‑Allyl Anilines: Synthesis of Benzylated Indolines. Journal of Organic Chemistry, 2019, 84, 6072–6083.
8. Deqiang Liang,* Bojie Huo, Yongrui Dong, Yan Wang, Ying Dong, Baoling Wang, Yinhai Ma, Copper-Catalyzed Alkylarylation of Unactivated Alkenes: Synthesis of 3‑Alkyl Indolines from N-Allyl Anilines and Alkanes. Chemistry-An Asian Journal, 2019, 14, 1932–1936.
9. Dandan Li,* Yan Wang, Zhenzhen Jia, Zhaocheng Ou, Yongrui Dong, Cunjie Lv, Guangbin Fu, Deqiang Liang,* Cu-Mediated Synthesis of Indolines and Dihydroisoquinolinones through Arylperfluoroalkylation of Unactivated Alkenes. European Journal of Organic Chemistry, 2019, 4797–4804.
10. Deqiang Liang,* Xuemei Song, Lichun Xu, Yitong Sun, Ying Dong, Baoling Wang, Weili Li, Synthesis of cyanoalkyl indolines through cyanoalkylarylation of N-allyl anilines with alkyl nitriles under metal-free and neutral conditions. Tetrahedron, 2019, 75, 3495–3503.
11. Xiufang Wang, Xiaohui Zhao, Xiulan Li, Bojie Huo, Ying Dong, Deqiang Liang,* Yinhai Ma, Brønsted acid-catalyzed radical C–H functionalization of acetone with N-allyl anilines to give 3-(3-oxobutyl)indolines. Tetrahedron Letters, 2019, 60, 1306–1310.
12. Yubin Ji, Siping Yang, Shiyi Lin, Yan Wang, Chenfeng Ji, Yingjie Liu,* Deqiang Liang,* Synthesis of 2,3-Dihydrotryptamines from Amide Solvents and Acyclic Materials through Metal-Free Amidoalkylarylation of Unactivated Alkenes. Synlett, 2019, 30, 1329–1333.
13. Enrui Dai, Qing Luo, Chunlin Chen, Fengyuan Ying, Ying Dong, Yingjie Liu,* Baoling Wang, Yinhai Ma, Deqiang Liang,* Copper-Catalyzed Cyanoisopropylalkenylation of N-Alkenylacrylamides to Give 1,3-Dihydropyrrol-2-ones. Chinese Journal of Organic Chemistry(有机化学), 2019, 39, 3524–3531.
14. Wenlan Li, Yitong Sun, Yongchao Yao, Ying Xu, Peng Li, Yingjie Liu,* Deqiang Liang,* Synthesis of Polychloromethyl-Containing Indolines via Metal-Free Radical Arylpolychloromethylation of Unactivated Alkenes. Chinese Journal of Organic Chemistry(有机化学), 2019, 39, 1727–1734.
15. Yanni Li, Yanping Li, Yuan Li, Chunlin Chen, Fengyuan Ying, Ying Dong, Deqiang Liang,* Metal-free cross-dehydrogenative C–N coupling of azoles with xanthenes and related activated arylmethylenes. Synthetic Communications, 2019, 46, 2053–2065.
16. Yanni Li, Ruirong Yang, Xiaohui Zhao, Yongchao Yao, Siping Yang, Qiong Wu, Deqiang Liang,* Copper-catalyzed cyanoisopropylation of beta-keto esters using azos: synthesis of betadicarbonyls bearing an alfa-tertiary nitrile moiety. Synthetic Communications, 2019, 46, 735–743.
17. Yanni Li, Yu Chang, Yufen Li, Cheng Cao, Jinshuang Yang, Baoling Wang, Deqiang Liang,* Iron-Catalyzed exo-Selective Synthesis of Cyanoalkyl Indolines via Cyanoisopropylarylation of Unactivated Alkenes. Advanced Synthesis & Catalysis, 2018, 360, 2488–2492.
18. Deqiang Liang,* Qishan Dong, Penghui Xu, Ying Dong, Weili Li, Yinhai Ma, Synthesis of CF3CH2-Containing Indolines by Transition-Metal-Free Aryltrifluoromethylation of Unactivated Alkenes. Journal of Organic Chemistry, 2018, 83, 11978−11986.
19. Deqiang Liang,* Dandan Ge, Yanping Lv, Wenzhong Huang, Baoling Wang, Weili Li, Silver-Catalyzed Radical Arylphosphorylation of Unactivated Alkenes: Synthesis of 3-Phosphonoalkyl Indolines. Journal of Organic Chemistry, 2018, 83, 4681–4691.
20. Deqiang Liang,* Yanni Li, Shulin Gao,* Renlun Li, Xiangguang Li, Baoling Wang, Hai Yang, Amide-Assisted Radical Strategy: Metal-Free Direct Fluorination of Arenes in Aqueous Media, Green Chemistry, 2017, 19, 3344–3349.
21. Yanni Li, Deqiang Liang,* Yu Chang, Xiangguang Li, Shaoguang Fu, Yunli Yuan, Baoling Wang, Metal-free and selective cleavage of unstrained carbon–carbon single bonds: Synthesis of β-ketosulfones from β-chlorohydrins and sodium sulfinates, Synthetic Communications, 2017, 47, 2044–2052.
22. Yanni Li, Deqiang Liang,* Xiangguang Li, Wenzhong Huang, Lin Yuan, Baoling Wang, Ping Cheng, Br2- or HBr-catalyzed synthesis of asymmetric 3,3-di(indolyl)indolin-2-ones, Heterocyclic Communications, 2017, 23, 29–34.
23. Deqiang Liang,* Xiangguang Li, Yanni Li, Yungang Yang, Shulin Gao,* Ping Cheng, Br2-Catalyzed Regioselective Dehydrative Coupling of Indoles with Acyloins: Direct Synthesis of α-(3-Indolyl) Ketones, RSC Advances, 2016, 6, 29020–29025.
24. Deqiang Liang,* Xiangguang Li,* Chaowu Wang, Qishan Dong, Baoling Wang, Hai Wang, Regioselective and efficient bromination of anilides on water using HBr and Selectfluor, Tetrahedron Letters 2016, 57, 5390–5394.
25. Deqiang Liang,* Xiangguang Li, Qing Lan, Wenzhong Huang, Lin Yuan, Yinhai Ma, Tin Tetrachloride Pentahydrate-Catalyzed Regioselective Chlorohydroxylation of α,β-Unsaturated Ketones in Water with Selectfluor as a Chlorine Source, Tetrahedron Letters, 2016, 57, 2207–2210.
26. Deqiang Liang,* Xiangguang Li, Wanshun Zhang, Yanni Li,* Mi Zhang, Ping Cheng, Br2 as a Novel Lewis Acid Catalyst for Friedel–Crafts Alkylation of Indoles with α,b-Unsaturated Ketones, Tetrahedron Letters, 2016, 57, 1027–1030.
27. Deqiang Liang,* Xiangguang Li, Juan Yang, Yanni Li,* Baoling Wang, Ping Cheng, Experimental and theoretical study of I2-catalyzed dialkenyl oxindoles synthesis from isatins and α-cyano ketene ethylene dithioacetal, Synthetic Communications, 2016, 46, 1924–1931.
28. Deqiang Liang,* Jingjing Li, Yanni Li,* Baoling Wang, Ping Cheng, Sha Luo, Novel and Potent Lewis Acid Catalyst: Br2-Catalyzed Friedel–Crafts Reactions of Naphthols with Aldehydes, Synthetic Communications, 2016, 46, 379–385.
29. Xiangguang Li,* Deqiang Liang,* Wenzhong Huang, Hongfu Zhou, Zhao Li, Baoling Wang, Yinhai Ma, Hai Wang, Visible light-induced carbonylation of indoles with arylsulfonyl chlorides and CO, Tetrahedron, 2016, 72, 8442–8448.
30. Wenzhong Huang, Juan Yang, Xiangguang Li, Lin Yuan, Yinhai Ma, Qinglong Zhou, Deqiang Liang,* Catalyst-Free Synthesis of 3-(1-Arylsulfonylalkyl)indoles via Three-Component Reaction of Indoles, Carbonyls, and Arenesulfinic Acids, Phosphorus, Sulfur, and Silicon and the Related Elements, 2016, 191, 772–777.
31. Wenzhong Huang, Lingli Nang, Xiangguang Li, Lin Yuan, Yinhai Ma, Deqiang Liang,* Bromine/para-Toluenesulfonic Acid-Catalyzed Synthesis of 3,3-Bis(indole-3-yl)indoline-2-(1H)-ones by Condensing Indoles with Isatins, Chinese Journal of Chemistry, 2015, 33, 1167–1172.
32. Deqiang Liang*, Wenzhong Huang*, Lin Yuan, Yinhai Ma, Jingmei Ma, Deman Ning, An underrated cheap Lewis acid: Molecular bromine as a robust catalyst for bis(indolyl)methanes synthesis, Catalysis Communications, 2014, 55, 11–14.
33. Deqiang Liang, Mang Wang*, Ying Dong, Yaru Guo, Qun Liu*, Palladium-catalyzed oxidative C-O cross-coupling of ketene dithioacetals and carboxylic acids, RSC Advances, 2014, 4, 6564–6567.
34. Deqiang Liang*, Wenzhong Huang*, Lin Yuan, Yinhai Ma, Liping Ouyang, Yuqin Rao, Yuxian Yang, Three-component reactions of ketene dithioacetals, aldehydes, and arenesulfinic acids: facile synthesis of allylic sulfones, Synthetic Communications, 2014, 44, 1930–1937.
35. Deqiang Liang, Mang Wang*, Bahargul Bekturhun, Binbin Xiong, Qun Liu*, One-Pot Synthesis of Polyfunctionalized 4H-Chromenes and Dihydrocoumarins Based on Copper(II) Bromide-Catalyzed C–C Coupling of Benzylic Alcohols with Ketene Dithioacetals, Advanced Synthesis & Catalysis, 2010, 352, 1593–1599.
八、授权发明专利
1. 梁德强,马忠校,胡筱,王宝玲,李维莉,一种电化学氧化合成2-氨基-1,3,4-噻二唑衍生物的方法,中国发明专利,CN 112981436 B,2022年02月01日
2. 梁德强,王宝玲,李维莉,马银海,含CF3吲哚啉和1,2,3,4-四氢异喹啉的合成方法,中国发明专利,CN 109081800 B,2021年10月01日
3. 梁德强,王宝玲,李维莉,马银海,一种铁催化的氰烷基吲哚啉及其制备方法,中国发明专利,CN 108440373 B,2021年5月14日
4. 梁德强,杨锐蓉,王宝玲,李维莉,马银海,一类α-三级腈结构β-二羰基化合物的合成方法,中国发明专利,CN 109232316 B,2021年3月26日
5. 梁德强,王宝玲,李维莉,马银海,一种银催化的3-膦酰甲基吲哚啉及制备方法,中国发明专利,CN 108383875 B,2020年4月28日
九、联系方式
电话:0871-65098482;QQ:251426210;
邮件:ldq五八七一@一二六.com(中文数字改为阿拉伯数字)
十、其他内容
实验室公众号:
创新团队网站:https://hgsys3.kmu.edu.cn/
课题组网站:https://www.x-mol.com/groups/liang_deqiang